Quantifying the role of mineral bridges on the fracture resistance of nacre-like composites.
- Grossman M Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland.
- Bouville F Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland.
- Masania K Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland kunal.masania@mat.ethz.ch andre.studart@mat.ethz.ch.
- Studart AR Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland kunal.masania@mat.ethz.ch andre.studart@mat.ethz.ch.
- 2018-11-28
Published in:
- Proceedings of the National Academy of Sciences of the United States of America. - 2018
English
The nacreous layer of mollusk shells holds design concepts that can effectively enhance the fracture resistance of lightweight brittle materials. Mineral bridges are known to increase the fracture resistance of nacre-inspired materials, but their role is difficult to quantify due to the lack of experimental systems where only this parameter is controllably varied. In this study, we fabricate tunable nacre-like composites that are used as a model to experimentally quantify the influence of the density of mineral bridges alone on the fracture properties of nacre-like architectures. The composites exhibit a brick-and-mortar architecture comprising highly aligned alumina platelets that are interconnected by titania mineral bridges and infiltrated by an epoxy organic phase. By combining experimental mechanical data with image analysis of such composite microstructures, an analytical model is put forward based on a simple balance of forces acting on an individual bridged platelet. Based on this model, we predict the flexural strength of the nacre-like composite to scale linearly with the density of mineral bridges, as long as the mineral interconnectivity is low enough to keep fracture in a platelet pullout mode. Increasing the mineral interconnectivity beyond this limit leads to platelet fracture and catastrophic failure of the composite. This structure-property correlation provides powerful quantitative guidelines for the design of lightweight brittle materials with enhanced fracture resistance. We illustrate this potential by fabricating nacre-like bulk composites with unparalleled flexural strength combined with noncatastrophic failure.
- Language
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- English
- Open access status
- bronze
- Identifiers
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- DOI 10.1073/pnas.1805094115
- PMID 30478055
- Persistent URL
- https://folia.unifr.ch/global/documents/294067
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