![Acrylate-Assisted Arene-Chromium Bond Cleavage: Generation of a [Cr(CO)2 ] Fragment under Mild Conditions.](/static/images/no-image.png)
Journal article
Acrylate-Assisted Arene-Chromium Bond Cleavage: Generation of a [Cr(CO)2 ] Fragment under Mild Conditions.
- Kündig EP Département de Chimie Organique, Université de Genève, 30 Quai Ernest Ansermet, CH-1211 Genève 4 (Switzerland), Fax: (+41) 22-328-7396.
- Kondratenko M Département de Chimie Organique, Université de Genève, 30 Quai Ernest Ansermet, CH-1211 Genève 4 (Switzerland), Fax: (+41) 22-328-7396.
- Romanens P Département de Chimie Organique, Université de Genève, 30 Quai Ernest Ansermet, CH-1211 Genève 4 (Switzerland), Fax: (+41) 22-328-7396.
- 2018-05-02
Published in:
- Angewandte Chemie (International ed. in English). - 1998
English
Displacement of the benzene ligand in 1 surprisingly occurs more readily than that of the methyl acrylate ligand. This paves the way for 1 to undergo arene exchange and arene substitution reactions, which may be triggered by a η2 →η4 haptotropic rearrangement of the acrylate. Complex 1 is thus a mild precursor of the highly unsaturated fragments [Cr(CO)2 ] (see scheme) and [Cr(CO)2 (η2 -acrylate)].
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1002/(SICI)1521-3773(19981204)37:22<3146::AID-ANIE3146>3.0.CO;2-M
- PMID 29711326
- Persistent URL
- https://folia.unifr.ch/global/documents/213769
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