Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
- Bădoiu, Andrei 1Department of Organic Chemistry, University of Geneva, Sciences II,30 quai Ernest Ansermet, CH-1211 Geneva 4, Switzerland
- Brinkmann, Yasmin 1Department of Organic Chemistry, University of Geneva, Sciences II,30 quai Ernest Ansermet, CH-1211 Geneva 4, Switzerland
- Viton, Florian 1Department of Organic Chemistry, University of Geneva, Sciences II,30 quai Ernest Ansermet, CH-1211 Geneva 4, Switzerland
- Kündig, E. Peter 1Department of Organic Chemistry, University of Geneva, Sciences II,30 quai Ernest Ansermet, CH-1211 Geneva 4, Switzerland
Published in:
- Pure and Applied Chemistry. - Walter de Gruyter GmbH. - 2008, vol. 80, no. 5, p. 1013-1018
English
Highly tuned, one-point binding chiral iron and ruthenium complexes selectively coordinate and activate α,β-unsaturated aldehydes and ketones toward asymmetric catalytic Diels-Alder cycloaddition reactions. Here we focus on the application of these transition-metal Lewis acids to asymmetric catalytic 1,3-dipolar cycloaddition reaction between enals and cyclic and acyclic nitrones as well as aryl nitrile oxides to give isoxazolidines and isoxazolines, respectively.
- Language
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- English
- Open access status
- green
- Identifiers
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- DOI 10.1351/pac200880051013
- ISSN 1365-3075
- Persistent URL
- https://folia.unifr.ch/global/documents/149698
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