Deneva, Vera Dobrikov, Georgi Crochet, Aurélien Nedeltcheva, Daniela Fromm, Katharina M. Antonov, Liudmil 2019-08-08 The concept for sensing systems using the tautomerism as elementary signaling process has been further developed by synthesizing a ligand containing 4- (phenyldiazenyl)naphthalene-1-ol as a tautomeric block and an amide group as metal capturing antenna. Although it has been expected that the intramolecular hydrogen bonding (between the tautomeric hydroxy group and the nitrogen atom from the amide group) could stabilize the pure enol form in some solvents, the keto tautomer is also observed. This is a result from the formation of intramolecular associates in some solvents. Strong bathochromic and hyperchromic effects in the visible spectra accompany the 1:1 formation of complexes with some alkaline earth metal ions. application/pdf https://folia.unifr.ch/global/documents/307990 https://folia.unifr.ch/documents/307990/files/fro_tps.pdf https://folia.unifr.ch/documents/307990/files/fro_tps_sm.pdf eng info:eu-repo/semantics/altIdentifier/doi/10.3762/bjoc.15.185 info:eu-repo/semantics/openAccess License undefined Beilstein Journal of Organic Chemistry. - 2019, vol. 15, no. 1, p. 1898–1906 info:eu-repo/classification/udc/54 Tautomerism as primary signaling mechanism in metal sensing: the case of amide group http://purl.org/coar/resource_type/c_6501