Pal, Subhajit Lucarini, Fiorella Ruggi, Albert Kilbinger, Andreas F. M. 2018-03-07 Enyne ring closing metathesis has been used to synthesize functional group carrying metathesis catalysts from a commercial (Ru-benzylidene) Grubbs’ catalysts. The new Grubbs-type ruthenium carbene was used to synthesize living heterotelechelic ROMP polymers without any intermediate purification. Olefin metathesis with a mono substituted alkyne followed by ring closing metathesis with an allylic ether provided efficient access to new functional group carrying metathesis catalysts. Different functional benzylidene and alkylidene derivatives have been investigated in the synthesis of heterotelechelic polymers in one pot. application/pdf https://folia.unifr.ch/global/documents/307109 https://folia.unifr.ch/documents/307109/files/kil_fmc.pdf https://folia.unifr.ch/documents/307109/files/kil_fmc_sm.pdf eng info:eu-repo/semantics/altIdentifier/doi/10.1021/jacs.7b12805 info:eu-repo/semantics/openAccess License undefined Journal of the American Chemical Society. - 2018, vol. 140, no. 9, p. 3181–3185 info:eu-repo/classification/udc/54 Functional metathesis catalyst through ring closing enyne metathesis: one pot protocol for living heterotelechelic polymers http://purl.org/coar/resource_type/c_6501