<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Lucarini, Fiorella</dc:creator>
  <dc:creator>Pastore, Mariachiara</dc:creator>
  <dc:creator>Vasylevskyi, Serhii</dc:creator>
  <dc:creator>Varisco, Massimo</dc:creator>
  <dc:creator>Solari, Euro</dc:creator>
  <dc:creator>Crochet, Aurélien</dc:creator>
  <dc:creator>Fromm, Katharina M.</dc:creator>
  <dc:creator>Zobi, Fabio</dc:creator>
  <dc:creator>Ruggi, Albert</dc:creator>
  <dc:date>2017-01-01</dc:date>
  <dc:description xmlns:ns0="xml" ns0:lang="en">The first heptacoordinate cobalt catalyst for light-driven hydrogen production in water  has been synthesized and characterized. Photochemical experiments using  [Ru(bpy)₃]²⁺ as photosensitizer gave a turnover number (TON) of 16300 mol H₂ (mol   cat.)⁻¹ achieved in 2 hours of irradiation with visible (475 nm) light. This promising  result provides a path forward in the development of new structures to improve the  efficiency of the catalysis.</dc:description>
  <dc:format>application/pdf</dc:format>
  <dc:identifier>https://folia.unifr.ch/global/documents/305558</dc:identifier>
  <dc:identifier>https://folia.unifr.ch/documents/305558/files/luc_hcc.pdf</dc:identifier>
  <dc:language>eng</dc:language>
  <dc:relation>info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201701427</dc:relation>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>License undefined</dc:rights>
  <dc:source>Chemistry - A European Journal. - 2017, vol. 23, no. 28, p. 6768-6771</dc:source>
  <dc:subject>info:eu-repo/classification/udc/54</dc:subject>
  <dc:title xmlns:ns1="xml" ns1:lang="en">Heptacoordinate Coii complex: a new architecture for photochemical hydrogen production</dc:title>
  <dc:type>http://purl.org/coar/resource_type/c_6501</dc:type>
</oai_dc:dc>