<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Błachucki, Wojciech</dc:creator>
  <dc:creator>Szlachetko, Jakub</dc:creator>
  <dc:creator>Kayser, Yves</dc:creator>
  <dc:creator>Dousse, Jean-Claude</dc:creator>
  <dc:creator>Hoszowska, Joanna</dc:creator>
  <dc:creator>Fernandes, Daniel L. A.</dc:creator>
  <dc:creator>Sá, Jacinto</dc:creator>
  <dc:date>2015-07-08</dc:date>
  <dc:description xmlns:ns0="xml" ns0:lang="en">We report on the reactivity of grafted tantalum organometallic catalysts with molecular oxygen. The changes in the local Ta electronic structure were followed by in situ high-energy resolution off-resonant spectroscopy (HEROS). The results revealed agglomeration and formation of Ta dimers, which cannot be reversed. The process occurs independently of starting grafted complex.</dc:description>
  <dc:format>application/pdf</dc:format>
  <dc:identifier>https://folia.unifr.ch/global/documents/304446</dc:identifier>
  <dc:identifier>https://folia.unifr.ch/documents/304446/files/dou_srs.pdf</dc:identifier>
  <dc:language>eng</dc:language>
  <dc:relation>info:eu-repo/semantics/altIdentifier/doi/10.1039/C5CP02950C</dc:relation>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>License undefined</dc:rights>
  <dc:source>Physical Chemistry Chemical Physics. - 2015, vol. 17, no. 28, p. 18262–18264</dc:source>
  <dc:subject>info:eu-repo/classification/udc/53</dc:subject>
  <dc:title xmlns:ns1="xml" ns1:lang="en">Study of the reactivity of silica supported tantalum catalysts with oxygen followed by in situ HEROS</dc:title>
  <dc:type>http://purl.org/coar/resource_type/c_6501</dc:type>
</oai_dc:dc>