<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Gschwind, Fabienne</dc:creator>
  <dc:creator>Sereda, Olha</dc:creator>
  <dc:creator>Fromm, Katharina M.</dc:creator>
  <dc:date>2009-10-14</dc:date>
  <dc:description xmlns:ns0="xml" ns0:lang="en">The multitopic ligand O,O′-bisnicotinic acid tetraethylene glycol, &lt;b&gt;L&lt;/b&gt;, was designed for the coordination of two distinct types of metal ions. In this work, we describe how the O-donor part of &lt;b&gt;L&lt;/b&gt; is used to coordinate to alkaline earth metal ions and that the N-donor atoms of &lt;b&gt;L&lt;/b&gt; bind to group 11 elements. This makes &lt;b&gt;L&lt;/b&gt; a suitable ligand for the combination of both metal ion types within the same compound. This concept will be exemplified by highlighting the pure Ca²⁺ complexes, a Cu⁺-coordination polymer network, as well as the mixed-metal compound, which can be used as a single-source precursor for mixed-metal oxide materials.</dc:description>
  <dc:format>application/pdf</dc:format>
  <dc:identifier>https://folia.unifr.ch/global/documents/301246</dc:identifier>
  <dc:identifier>https://folia.unifr.ch/documents/301246/files/fromm_mld.pdf</dc:identifier>
  <dc:identifier>https://folia.unifr.ch/documents/301246/files/fromm_mld_sm.pdf</dc:identifier>
  <dc:identifier>https://folia.unifr.ch/documents/301246/files/fromm_mld_sm.cif.txt</dc:identifier>
  <dc:language>eng</dc:language>
  <dc:relation>info:eu-repo/semantics/altIdentifier/doi/10.1021/ic9009064</dc:relation>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>License undefined</dc:rights>
  <dc:source>Inorganic Chemistry. - 2009, vol. 48, no. 22, p. 10535–10547</dc:source>
  <dc:subject>info:eu-repo/classification/udc/54</dc:subject>
  <dc:title xmlns:ns1="xml" ns1:lang="en">Multitopic ligand design: a concept for single-source precursors</dc:title>
  <dc:type>http://purl.org/coar/resource_type/c_6501</dc:type>
</oai_dc:dc>
