Brochon, Cyril Sary, Nicolas Mezzenga, Raffaele Ngov, Chheng Richard, Fanny May, Michaël Hadziioannou, Georges 2008-09-17 Atom transfer radical polymerization (ATRP) was used as a versatile route to well-defined poly(diethylhexyl-p-phenylenevinylene-b-styrene) (PPV-b-PS) semiconducting block copolymers. For this purpose, original conjugated macroinitiators were synthesized from DEH-PPV and further used for the copolymerization reaction. The microphase-separated morphologies obtained with the semiconducting PPV-b-PS block copolymer fulfill the basic structural requirements required to build efficient organic photovoltaic devices. application/pdf https://folia.unifr.ch/global/documents/301061 https://folia.unifr.ch/documents/301061/files/sary_spp.pdf eng info:eu-repo/semantics/altIdentifier/doi/10.1002/app.28960 info:eu-repo/semantics/openAccess License undefined Journal of Applied Polymer Science. - 2008, vol. 110, no. 6, p. 3664 - 3670 PPV semiconducting polymer ATRP rod-coil block copolymer self-assembly photovoltaic polymer materials info:eu-repo/classification/udc/53 Synthesis of poly(paraphenylene vinylene) - polystyrene-based rod-coil block copolymer by atom transfer radical polymerization: Toward a self-organized lamellar semiconducting material http://purl.org/coar/resource_type/c_6501